Oracle Expert

Say our target table is called XML_REPOSITORY

create table xml_repository
(file_name varchar2(30),
 xml clob);

Create a control file like this

load data
infile *
append into table xml_repository
(
file_name char(30),
xml lobfile (file_name) terminated by eof
)
begindata
file1.xml
file2.xml
file3.xml

Then prepare your xml files as listed above. This can be images or word document, etc (obviously with corresponding BLOB)

Then as usual

sqlldr userid/password@db control=loadxml.ctl